∵等比数列{an}的前n项和为Sn,a3=-2,S4=3S2,∴a1+a2+a3+a4=3(a1+a2)∴a3+a4=2(a1+a2),∴q2=2,∴a3=a1q2=a1×2=2,∴a1=1∴a7=a1q6=1×23=8故答案为:8